Britain looked to be heading for their first final in the competition since 1981 when Emma Raducanu defeated Viktoria Hruncakova 6-4 6-4 and Katie Boulter won the opening set against Rebecca Sramkova.
Neither had dropped a set all week until that point but Boulter could not maintain her advantage and Sramkova fought back to claim a 2-6 6-4 6-4 victory and send the tie to a deciding doubles.
Called into action for the first time all week, Heather Watson and Olivia Nicholls were caught cold by Hruncakova and Tereza Mihalikova and fell to a one-sided 6-2 6-2 defeat.
Slovakia will now take on Italy for the title, while Britain must reflect on a disappointing end to what has nevertheless been a positive campaign.
In particular, the performances of Raducanu shows that Britain can hope to challenge for the title again in the near future.
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