Defending champion Djokovic can become the oldest Open era champion at the tournament if he secures a fifth title, a record he would share with Jimmy Connors, Pete Sampras and Roger Federer.
The 37-year-old would also move to 25 Grand Slam triumphs, taking him clear of the 24 he currently shares with Margaret Court.
The final major of the year comes at a critical time for Djokovic.
This year he was succeeded as Australian Open champion by Sinner, who also relieved him of his world No 1 ranking.
Carlos Alcaraz took his French Open title, with the Spanish crowd-pleaser then sweeping Djokovic off court in a one-sided Wimbledon final.
However, Djokovic, returned to the clay courts of Roland Garros to stun Alcaraz in the Olympic final.
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