Valencia Mayor María José Catalá said that the danger of the 14-story building collapsing and the intense heat from the fire initially prevented emergency workers from getting in to search for possible survivors.
The fire started Thursday evening and quickly engulfed the buildings. Experts said that the building's polyurethane cladding may have contributed to the fire's ferocity.
Dramatic images showed clouds of black smoke as the flames consumed the high rise of 138 flats in the Campanar district of the Mediterranean port city.
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