MELBOURNE:
But home favourite Nick Kyrgios will not join them as the combustible Australian failed to clear the first hurdle, swearing and in pain.
In the women's draw, Iga Swiatek and Coco Gauff powered through with minimum fuss as they seek to dethrone two-time defending champion Aryna Sabalenka.
On a blockbuster second day in Melbourne, Djokovic lost the first set to 107th-ranked American Nishesh Basavareddy in the prime-time evening match on Rod Laver Arena.
But the Serbian great, hoping to roll back the years and win an 11th Australian Open and record 25th Grand Slam singles title, recovered to pull through 4-6, 6-3, 6-4, 6-2.
Djokovic was animated at the end and struggled to raise a smile.
Italian world number one Sinner was playing under a cloud after twice testing positive for traces of a steroid in March.
He denies wrongdoing and was cleared by tennis authorities, but the World Anti-Doping Agency (WADA) appealed and is seeking to ban him for up to two years.
Sinner was warmly welcomed defeating Chile's Nicolas Jarry 7-6 (7/2), 7-6 (7/5), 6-1.
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