The South Korean reeled off three birdies in a row starting at the 11th hole and sank eight birdies overall to finish one ahead of American Angel Yin, who made a long eagle putt from the fringe at the par-five 17th to sit second.
"I played well," An said. "My putting was really good. The speed was good and the shape was good. I was just trying to focus a little bit more."
Americans Marina Alex and Allisen Corpuz shared third on 66.
The top 60 players in the season points chase qualified for the US$11 million (S$14.8 million) showdown, with a US$4 million top prize at Tiburon Golf Club in Naples, Florida.
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HUT TO ART IN ZIMBABWE
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