A boy aged 16 and a 27-year-old woman were also injured after the substance, believed to be acidic, was thrown at the victims outside Westminster Academy on Monday afternoon.
Police believe the teenagers were approached by a lone suspect who was on an e-scooter, with a member of staff left injured after she rushed to help.
Officers on patrol were flagged down by school staff following the incident in Alfred Road, Westbourne Park, shortly after 4.40pm.
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